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Listar por autor "Rodríguez, Amor"
Mostrando ítems 1-12 de 12
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Artículo
Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different
Ríos Moreno, Pablo; Rodríguez, Amor; Conejero, Salvador (Royal Society of Chemistry, 2022)In this Perspective we discuss the ability of transition metal complexes to activate and cleave the Si–H and B–H bonds of ...
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Ambiphilic boryl groups in a neutral Ni(ii) complex: a new activation mode of H2
Ríos Moreno, Pablo; Borge, Javier; Fernández de Córdova Martín, Francisco José; Sciortino, Giuseppe; Lledós, Agustí; Rodríguez, Amor (Royal Society of Chemistry, 2021)The concept of metal–ligand cooperation opens new avenues for the design of catalytic systems that may offer alternative ...
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An Unsaturated Four-Coordinate Dimethyl Dimolybdenum Complex with a Molybdenum–Molybdenum Quadruple Bond
Curado, Natalia; Carrasco, Mario; Campos, Jesús; Maya Díaz, Celia María; Rodríguez, Amor; Ruiz, E.; Álvarez, Santiago; Carmona Guzmán, Ernesto (John Wiley & Sons, 2017)We describe the synthesis and the molecular and electronic structures of the complex [Mo2Me2{μ‐HC(NDipp)2}2] (2; ...
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Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation
Ríos Moreno, Pablo; Díez, Josefina; López Serrano, Joaquín; Rodríguez, Amor; Conejero, Salvador (John Wiley & Sons, 2016)The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes ...
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Cleavage of Carbon Dioxide C=O Bond Promoted by Nickel-Boron Cooperativity in a PBP-Ni Complex
Álvarez Rodríguez, Lucía; Ríos Moreno, Pablo; Laglera Gandara, Carlos J.; Jurado, Andrea; Fernández de Córdova, Francisco José; Gunnoe, T. Brent; Rodríguez, Amor (Wiley-Blackwell, 2023)The synthesis and characterization of (tBuPBP)Ni(OAc) (5) by insertion of carbon dioxide into the Ni−C bond of (tBuPBP)NiMe ...
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Enhancing the catalytic properties of well-defined electrophilic platinum complexes
Ríos Moreno, Pablo; Rodríguez, Amor; Conejero, Salvador (Royal Society of Chemistry, 2020)Platinum complexes have been often considered as the least reactive of the group 10 triad metals. Slow kinetics are behind ...
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Experimental and Computational Studies of the Molybdenum-Flanking Arene Interaction in Quadruply Bonded Dimolybdenum Complexes with Terphenyl Ligands
Carrasco, Mario; Mendoza, Irene; Álvarez González, Eleuterio; Grirrane, Abdessamad; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; Falceto, Andrés; Álvarez, Santiago; Carmona Durán, Ernesto (Wiley, 2015)To clarify the nature of the Mo[BOND]Carene interaction in terphenyl complexes with quadruple Mo[BOND]Mo bonds, ether ...
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Hydrosilylation of Carbonyl Compounds Catalyzed by a Nickel Complex Bearing a PBP Ligand
Fernández, José Antonio; García, Juan Manuel; Ríos Moreno, Pablo; Rodríguez, Amor (Wiley, 2021)The efficient catalytic hydrosilylation of ketones and aldehydes has been investigated using a nickel pincer hydride complex ...
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Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
Curado, Natalia; Carrasco, Mario; Álvarez González, Eleuterio; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; López Serrano, Joaquín; Carmona Guzmán, Ernesto (American Chemical Society, 2015)New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ...
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Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex
Ríos Moreno, Pablo; Rodríguez, Amor; López Serrano, Joaquín (American Chemical Society, 2016)This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ...
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Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex
Ríos Moreno, Pablo; Curado, Natalia; López Serrano, Joaquín; Rodríguez, Amor (American Chemical Society, 2016)Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have ...
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Synthesis and structure of mixed carboxylate-aminopyridinate and -amidinate complexes of dimolybdenum and ditungsten
Mendoza, Irene; Curado, Natalia; Carrasco Delgado, Mario; Álvarez González, Eleuterio; Peloso, Riccardo; Rodríguez, Amor; Carmona Guzmán, Ernesto (Elsevier, 2015)We describe in this paper the synthesis and structural characterization of dimolybdenum and ditungsten complexes with MM ...